The Antarctic stratospheric ozone hole in 2024

by OnymousGuy

Abstract

The data says 2024 was pretty average, and "far from being fully healed", but NASA's press office says "relatively small". So which is it? "Relatively small", or "far from being fully healed"?

Background

We are approaching the end of season for this year's Antarctic stratospheric ozone hole, as the increasing springtime sunlight stimulates the Chapman cycle to produce more ozone. 

NASA's ozone watch documents the status of the Antarctic stratospheric ozone hole, with updates about every week or so, but less frequently at the end of the season. Certain parameters are tracked:

The data for the ozone hole area, the minimum ozone, and the minimum stratospheric temperature are available. Also available is a table of values showing the maximum ozone hole area and the minimum ozone values for each year...

The graphs ... show the progress of the ozone hole for 2024. The gray shading indicates the highest and lowest values measured since 1979. The red numbers are the maximum or minimum values. The stratospheric temperature and the amount of sunlight reaching the south polar region control the depth and size of the Antarctic ozone hole. The dashed line in the minimum temperature plot indicates the temperature below which Type I (NAT) PSCs can form. 

Ozone concentrations are reported in Dobson units.

The Dobson Unit (DU) is the unit of measure for total ozone. If you were to take all the ozone in a column of air stretching from the surface of the earth to space, and bring all that ozone to standard temperature (0 °Celsius) and pressure (1013.25 millibars, or one atmosphere, or “atm”), the column would be about 0.3 centimeters thick. Thus, the total ozone would be 0.3 atm-cm. To make the units easier to work with, the “Dobson Unit” is defined to be 0.001 atm-cm. Our 0.3 atm-cm would be 300 DU. 

Here are some recent images.

• ozone hole area, minimum ozone, minimum stratospheric temperature,

• annual maximum ozone hole area, annual minimum ozone.

Here is a recent false color image of the ozone hole. 

Discussion

From these figures, I would say that the 2024 ozone hole has been pretty close to its average over the satellite era. So I was a bit surprised to read this puffery from NASA:

Healing continues in the atmosphere over the Antarctic: a hole that opens annually in the ozone layer over Earth's southern pole was relatively small in 2024 compared to other years. 

During the peak of the ozone depletion season from Sept. 7 through Oct. 13, the 2024 area of the ozone hole ranked the seventh smallest since recovery began in 1992, when the Montreal Protocol, a landmark international agreement to phase out ozone-depleting chemicals, began to take effect...

The improvement is due to a combination of continuing declines in harmful chlorofluorocarbon (CFC) chemicals, along with an unexpected infusion of ozone carried by air currents from north of the Antarctic, scientists said. 

A little bit of realism creeps into the blurb from NASA, lower down in the press release.

In previous years, NASA and NOAA have reported the ozone hole ranking using a time frame dating back to 1979, when scientists began tracking Antarctic ozone levels with satellite data. Using that longer record, this year's hole ranked 20th smallest in area across the 45 years of observations.

IMO, 20th out of 45 sounds pretty average. One of the GML scientists spills the beans:

"For 2024, we can see that the ozone hole's severity is below average compared to other years in the past three decades, but the ozone layer is still far from being fully healed," said Stephen Montzka, senior scientist of the NOAA Global Monitoring Laboratory.

So which is it? "Relatively small", or "far from being fully healed"?

Ozone Depleting Substances

The ozone hole, of course, depends on the concentration of stratospheric chlorine and bromine; sources of atomic Cl and Br in the stratosphere are called ozone depleting substances. The Trump administration excised EPA information about ozone depletion and the like, so one must look to the European Union for such things.

A compound that contributes to stratospheric ozone depletion. Ozone-depleting substances (ODS) include CFCs, HCFCs, halons, methyl bromide, carbon tetrachloride, and methyl chloroform. ODS are generally very stable in the troposphere and only degrade under intense ultraviolet light in the stratosphere. When they break down, they release chlorine or bromine atoms, which then deplete ozone.

These species have one thing in common: they contain halogens, specifically chlorine or bromine. Each halogenated compound is associated with an ozone-depleting potential (ODP), a direct measure of its ability to destroy ozone. More from the EU:

The ozone-depleting potential (ODP) of a substance refers to the relative amount of ozone depletion caused by it. It is the ratio of the impact on ozone of the emission of a chemical substance to the impact of a similar emission by mass of CFC-11. The quantity in metric tonnes of a particular controlled substance is multiplied by its ODP to give its overall potential to deplete the ozone layer. For instance, 1 metric tonne of CFC-11 corresponds to 1 ODP tonnes (as its ODP is equal to 1), whilst for bromotrifluoromethane or halon 1301 (with an ODP = 10), 1 metric tonne corresponds to 10 ODP tonnes. The ODPs of controlled and new substances are listed in Annexes I and II of the Ozone Regulation (Regulation (EC) No 1005/2009). Some new substances have a range, rather than a single ODP value. In this online data viewer, the highest value of the ODP value range is used.

What are the current levels of atmospheric chlorine? NOAA's Global Monitoring Laboratory reports this trend.

It seems that the most that one could say, based on the data, is that mid-latitude amounts of ozone-depleting substances have dropped below half of their pre-Montreal Protocol maximum. Yes, the world is still on track to see Antarctic  mounts of ozone-depleting substances have dropped below half of their pre-protocol maxima by 2076 or so, provided that we remain vigilant in observing the protocols and their amendments. HCFCs are the issue.

And then NOAA scientists weigh in on the minimum.

NOAA scientists also release instrumented weather balloons from the South Pole Baseline Atmospheric Observatory to observe ozone concentrations directly overhead in a measurement called Dobson Units. The 2024 concentration reached its lowest value of 109 Dobson Units on October 5. The lowest value ever recorded over the South Pole was 92 Dobson Units in October 2006.

NASA and NOAA satellite observations of ozone concentrations cover the entire ozone hole, which can produce a slightly smaller value for the lowest Dobson Unit measurement.

"That is well below the 225 Dobson Units that was typical of the ozone cover above the Antarctic in 1979," said NOAA research chemist Bryan Johnson. "So, there's still a long way to go before atmospheric ozone is back to the levels before the advent of widespread CFC pollution." 

There you have, at the very end of the puff piece: "There's still a long way to go before atmospheric ozone is back to the levels before the advent of widespread CFC pollution."